It’s currently quite difficult to locate scrollbars, particularly at lower screen brightness and I think they would be much easier to see if either the bar or the background was made lighter than the overall window colour.
The problem is the scrollbar color is linked to the background color (gtk_background), and the selected scrollbar handle is linked to the darkest background color (gtk_darkest). So, unless something is changed in the Ardour’s code, for very dark themes this problem is impossible to fix.